Cookie settings

When you visit any website, that website may store or retrieve information about your browser, especially in the form of cookies. This information may relate to you, your preferences, your device, or it can be used to make the site work as you expect. This information usually doesn't identify you directly, but it allows you to get more personalized online content. In these settings, you can choose not to allow certain types of cookies. Click on the category headings to learn more and change your default settings. However, you should be aware that blocking certain cookies may affect your experience with the site and the services we may offer you.More info

Manage cookie settings

Necessary cookies

Always active

These cookies are necessary to ensure the functionality of the website and cannot be turned off in our systems. They are usually set up only in response to activities you perform that constitute a service-related request, such as setting privacy preferences, signing in, or filling out forms. You can set your browser to block or alert you to such cookies, in which case some parts of the site may not work.

Performance cookies

These cookies allow us to determine the number of visits and traffic sources so that we can measure and improve the performance of our site. They help us identify which sites are the most and least popular, and see how many visitors are moving around the site. All information that these cookies collect is aggregated and therefore anonymous. If you do not enable these cookies, we will not know when you visited our site.

Where to find me

Department of chemistry
Tajovského 40
97401 Slovensko

Professional characteristics

Educational Qualification:

  • Specialization: Organic Chemistry.
  • Ph D (eq, candidate of science): organic chemistry from Taras Shevchenko National University of Kyiv, Ukraine.
  • M. Sc.: First Class in Chemistry, Taras Shevchenko National University of Kyiv, Ukraine.
  • B. Sc.: Taras Shevchenko National University of Kyiv, Ukraine.

Languages Skils: Ukrainian (Native or bilingual proficiency), English (Professional proficiency), German (Full professional proficiency, C1 Goethe-Institute exam in the year 2011 (90,00/100, very good, Certificate number EFC1 037495, http://www.goethe.de/lrn/prj/pba/bes/gc1/enindex.htm), Russian (Native or bilingual proficiency), Polish (more or less), Slovak (B1 level).

  • 2009: Group leader (E14 position, grade 3) University of Rostock Institute of Chemistry, Department of Organic Chemistry;
  • 2013: Visiting Research Assistant Professor at Department of Chemistry University of Illinois at Chicago;
  • 2015: Principal Investigator, Head of the Laboratory of Homogeneous Catalysis and Molecular Design at Polish Academy of Sciences, Poland;
  • 2020: Visiting Professor at University of Salerno, Italy;

  • 2020: Senior Researcher at University of Helsinki, Finland;
  • 2020: Member of Helsinki Institute of Sustainability Science (HELSUS), Finland; https://researchportal.helsinki.fi/en/persons/viktor-iaroshenko 
  • 2021: UMB Docent (Associate Professor); 
  • 07.2022-09.2022: Visiting Faculty at Universität Osnabrück, Germany;
  • 09.2022: KTH-Royal Institute of Technology, Sweeden; https://www.kth.se/profile/viktiaro 
  • 09.2022: Wallenberg Wood Science Center, Sweeden; https://wwsc.se/wwsc-members/viktor-iaroshenko/ 
  • 02.2023-08.2023: Visiting Fellow at Ohio State University, USA, OH.
  • 01.2024: 

Scientific Interests:

  • Heterocyclic chemistry, element-organic chemistry, fluorine chemistry, phosphorus chemistry, metal-organic chemistry;
  • Molecular design, drug design, medicine chemistry, fluorine-containing bioactive molecules;
  • Synthesis of pollyfloroalkylcontaining purines, and their isoster analogues;
  • Domino reactions;
  • Transition metal chemistry;
  • Functionalization of C-H Bound;
  • Design of fine-tunable phosphine ligands for homogenous and organo-catalysis;
  • Photoredox catalysis, mechanochemistry, green chemistry, sustainability.

Professional Services:

Referee for the following journals:

J. Org. Chem., Org. Lett., Acc. Chem. Res., ACS Catalisys, Org. Process Res. Dev.,Org. Biomol. Chem., RCS Advances, Future Sci. OA., Adv. Synth. Catal., Catal. Sci. Technol., New J. Chem., Tetrahedron, Synthesis, Synlett, Current Organic Chemistry, act.

 

Teaching:

 Winter Semester: 

1. ORGANIC CHEMISTRY 1 (4 credits);

2. CATALYSIS AND SUSTAINABILITY IN CHEMISTRY (4 credits);

https://www.fpv.umb.sk/en/international-cooperation/ects-courses.html 

 

Summer Semester:

1. ORGANIC CHEMISTRY 2 (4 credits);

2. MEDICINAL CHEMISTRY AND DRUG DISCOVERY (4 credits);

https://www.fpv.umb.sk/en/international-cooperation/ects-courses.html 

 

Personal grants:

Since 2016 the actual grant-based budget is about 700 000 €.

 

2023:

09.2022: Knut and Alice Wallenberg Foundation (Sweden) https://kaw.wallenberg.org/en .

07.2022-12.2025:Agentúra na Podporu Výskumu a Vývoja. "Perfluóralkylácia - stratégia diverzifikácie komplexných organických molekúl v neskorej fáze syntézy.  Budget: ~220 000 €. Duration 42 months." Nr. APVV-21-0362. Role in the project – Principal Investigator, Project Manager. https://www.apvv.sk/ 

02.2017-02.2019: Narodowe Centrum Nauki, NCN-POLONEZ 2 Fellowship;Project title: “Design, bio and diversity-oriented synthesis of fused pyridin-4(1H)-ones, 4H-pyrane-4-ones and 4H-thiopyran-4-ones as potential preclinical drug-candidates”.  This grant from National Science Centre (NSC) Poland in the frames of European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No. 665778 (POLONEZ 2 grant, Nr. 2016/21/P/ST5/00630). Role in the project – Research Partner. The actual budget: 932 874 PLZ (~ 214 022 €). Obtained by Dr. Satenik Mkrtchyan member of “Homogeneous catalysis and molecular design” group at Center of Molecular and Macromolecular Studies, PAS. https://www.ncn.gov.pl/sites/default/files/listy-rankingowe/2016-03-15/streszczenia/331575-en.pdf

08.2016-08.2019: Narodowe Centrum Nauki, NCN-SONATA 10; Project title in Polish: „Katalizowane metalami przejściowymi ukierunkowane reakcje aktywacji wiązania C-H nitro-podstawionych związków aromatycznych i olefin wraz z dalszą transformacją grupy nitrowej.” Budget: 698 800 PLN (~158 000 € ). Duration: 36 months. Nr. 2015/19/D/ST5/02774. Role in the project – Principal Investigator, Project Manager. https://www.ncn.gov.pl/sites/default/files/listy-rankingowe/2015-09-15/streszczenia/309499-pl.pdf

Publication Statistic 2007-2022:

The number of peer-reviewed publications: 104 (74 are Q1);

The number of first authorships: 38; The number of second authorships: 16;

The number of corresponding authorships:  75. 

 (More than 2000 total citations, h-index = 29).

Scopus: http://www.scopus.com/authid/detail.url?authorId=23012226400

Google scholar: https://scholar.google.com/citations?hl=en&user=IbJQXagAAAAJ&view_op=list_works&sortby=pubdate 

 

Special Issues:

1. Molecules 2022 "Organofluorine Chemistry and Beyond"  Guest editor. 

2. Molecules 2023 "Modern Organophosphorus Chemistry"   Main guest editor with Dr. Satenik Mkrtchyan as co-editor.

3. Molecules 2023 "Recent Research on Cross-Coupling Reactions" Main guest editor with Dr. Michał Jakubczyk and Dr. Satenik Mkrtchyan as co-editors.

 

Books: 

Very Recent Papers: 

2020

1. Visible-light-mediated arylation of ortho-hydroxyarylenaminones: Direct access to isoflavones.

Satenik Mkrtchyan,* Viktor O. Iaroshenko*Chem. Commun. 2020, 56, 2606-2609. (Open access).

https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc09945j#!divAbstract

This article is part of the themed collection: Most popular organic chemistry articles

Highlighted at Organic Chemistry Portal: https://www.organic-chemistry.org/abstracts/lit8/548.shtm 

 

2. Photoredox functionalisation of 3-halogenchromones, 3-formylchromones and chromone-3-carboxilyc acids: Routes to 3-acylchromones.

Satenik Mkrtchyan,* Viktor O. Iaroshenko.* J. Org. Chem. 2020, 8511, 7152–7174.

https://pubs.acs.org/doi/10.1021/acs.joc.0c00537

 

2021

1. Arylation of ortho-hydroxyarylenaminones by sulfonium salts and arenesulfonyl chlorides: An access to isoflavones.

Satenik Mkrtchyan,* Viktor O. Iaroshenko* J. Org. Chem. 2021,86, 7, 4896–4916.

https://pubs.acs.org/doi/10.1021/acs.joc.0c02294

Highlighted at Organic Chemistry Portal: https://www.organic-chemistry.org/abstracts/lit7/863.shtm 

 

2. Cu-catalyzed arylation of bromo-difluoro-acetamides by aryl boronic acids, aryl trialkoxysilanes and dimethyl-aryl-sulfonium salts: New entries to aromatic amides.

Satenik Mkrtchyan,* Michał Jakubczyk,Suneel Lanka, Michael Pittelkow, Viktor O. Iaroshenko.* MPDI Molecules, 202126,2957. (Open Access). https://www.mdpi.com/1420-3049/26/10/2957

Part of the Special Issue "Organofluorine Chemistry and Beyond" edited by Dr. Viktor Iaroshenko.

https://www.mdpi.com/journal/molecules/special_issues/Organofluorine_Chemistry

 

3. Practical mechanochemical transformation of CF3 group: Synthesis of amides and Schiff bases.

Satenik Mkrtchyan,* Michał Jakubczyk, Suneel Lanka, Muhammad Yar, Khurshid Ayub, Mohanad Shkoor, Michael Pittelkow, Viktor O. Iaroshenko.* Adv. Synth. Catal. 2021, 21, 5448-5460. (Open access)

https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.202100538

 

4. Mechanochemical synthesis of aromatic sulfonamides via three-component TM-catalyzed coupling of appropriate SO2-source, arylation agents and amines.

Satenik Mkrtchyan, Viktor O. Iaroshenko.* Chem. Commun. 202157(84), 11029–11032.

https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc03224k 

 

2022

1. Structure, optical and electro-physical properties of tetramerized anion-radical salt (N-Xy-Qn)(TCNQ)2.

Bolesław Barszcz, Tetiana N. Starodub, Adam Mizera, Roman Świetlik, Karol Rytel, Viktor O. Iaroshenko, Vladimir A. Starodub. Spectrochim. Acta A. 2022, 270, 120822.

https://www.sciencedirect.com/science/article/abs/pii/S1386142521013998

 

2. Crystal Structure of Anion-Radical Salts of 7,7,8,8-Tetracyanoquinodimethane with N-xylyl-pyridinium and N-xylyl-isoquinolinium Cations.

T. N. Starodub,* D. Fenske, O. Fuhr, V. O. Iaroshenko, D. Stepen’. Crystallography Reports 202267,  356–363. DOI: 10.1134/S1063774522030191

 https://link.springer.com/article/10.1134/S1063774522030191

 

3. Mechanochemical Ni-catalysed arylation of ortho-hydroxyarylenaminones: Synthesis of isoflavones.

Satenik Mkrtchyan, Michał Jakubczyk, Suneel Lanka, Muhammad Yar, Tariq Mahmood, Khurshid Ayub, Mika Sillanpää, Christine M. Thomas, Viktor O. Iaroshenko.* Adv. Synth. Catal. 2022, b364, 3512–3535.

https://onlinelibrary.wiley.com/doi/10.1002/adsc.202200645  (Open access). 

Front Cover Picture: https://onlinelibrary.wiley.com/doi/10.1002/adsc.202200956 

 

4. Mechanochemical conversion of aromatic amines into aryl trifluoromethyl ethers. 

Michał Jakubczyk, Satenik Mkrtchyan,* Suneel Lanka, Mohanad Shkoor, Simon Budzak, Miroslav Iliaš,  Marek Skorsepa, Viktor O. Iaroshenko.*  J. Am. Chem. Soc. 2022, 144, 23, 10438–10445.

https://pubs.acs.org/doi/10.1021/jacs.2c02611 (Open Access). Among the "Most Read" articles of June 2022 – July 2022 (more then 15 K reads) in JACS.

Highlighted at Organic Chemistry Portal: https://www.organic-chemistry.org/abstracts/lit8/485.shtm 

 

2023

1. Nickel Catalyzed Mechanochemical Defluorinative Arylation of Trifluoroacetamides Enabled by Dysprosium(III) Oxide C-F bond activation: Facile entry to Aromatic Amides.

Satenik Mkrtchyan,* Mohanad Shkoor, Mandalaparthi Phanindrudu, Miroslav Medveď, Olena Sevastyanova, Viktor O. Iaroshenko.J. Org. Chem. 2023, 88, 2, 863–870.

 https://pubs.acs.org/doi/10.1021/acs.joc.2c02197 (Open access). Among the "Most Read" articles of Janury 2023 – Febraury 2023 (more then 2 K reads) in JOC

 

2. Metal-free Supramolecular Reduction of Nitro Compounds into the Cucurbit[7]uril Cavity: Testing the Enabling Technique in Aqueous Media.

Satenik Mkrtchyan, Vishal B. Purohit, Sehrish Sarfaraz, Khurshid Ayub,  Viktor O. Iaroshenko.ACS Sustainable Chem. Eng. 2023, 2023, 11, 23, 8406–8412.  (Open access). https://pubs.acs.org/doi/10.1021/acssuschemeng.3c00497

Among the "Most Read Articles" in ACS Sustainable Chemistry & Engineering, June 2023- .

https://pubs.acs.org/action/showMostReadArticles?topArticlesType=month&journalCode=ascecg 

 

3. Introducing trifluoromethyl group as halide surrogates in mechanochemical realizations of Ni-catalyzed cross-coupling reactions.

Satenik Mkrtchyan, Michał Jakubczyk, Šimon Budzák, Barbora Benická, Viktor O. Iaroshenko.* Asian J. Org. Chem. 202312(6), e202300094. https://onlinelibrary.wiley.com/doi/10.1002/ajoc.202300094 

 

4. Mechanochemical Defluorinative Cyanation of Trifluoromethylarenes. 

Satenik Mkrtchyan, Mohanad Shkoor, Sehrish Sarfaraz, Khurshid Ayub, Viktor O. Iaroshenko.* Org. Biomol. Chem., 202321, 6549–6555. https://pubs.rsc.org/en/Content/ArticleLanding/2023/OB/D3OB00787A

 

5.Mechanochemical acylation of ortho-hydroxyarylenaminones by CF3-compounds: Synthesis of 3-acylchromones.

Satenik Mkrtchyan*, Vishal B. Purohit, Jela Nociarova, Spartak Khutsishvili, Muhammad Yar, Tariq Mahmood, Khurshid Ayub, Simon Budzak, Marek Skoršepa,  Viktor O. Iaroshenko.*  Adv. Synth. Catal. 2023,  2026-2035. (Open access).

https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.202300260 

 

6. Nanocellulose as Convenient Reaction Media for Mechanochemical FeClmediated Synthesis of 3-Acylchromones. 

Satenik Mkrtchyan*, Vishal B. Purohit,  Viktor O. Iaroshenko.*  ACS Sustainable Chem. Eng. 2023, 11, 38, 13877–13884.

https://pubs.acs.org/doi/10.1021/acssuschemeng.3c03467 

 

2024

 

1. Nanocelulose as a reaction media for FCl3 mediated reductive functionalization of nitro compounds.

Satenik Mkrtchyan*, Vishal B. Purohit,  Jiří Zapletal, Oleksandr O. Shalimov, Viktor O. Iaroshenko.* ACS Sustainable Chem. Eng. 202412, 1, 1–9. (Open access).

https://pubs.acs.org/doi/10.1021/acssuschemeng.3c04372

 

2. One-step Ru-catalyzed conversion of phenolic OH groups to trifluoromethyl under mechanochemical conditions. Satenik Mkrtchyan,* Michał Jakubczyk, Sehrish Sarfaraz, Khurshid Ayub, Viktor O. Iaroshenko.* 2024, conditionally accepted. 

 

3. Mechanochemical Transformation of Aryltrimethylammonium Triflates, Aryldiazonium Tetrafluoroborates and Aryl Pinacolboranes to Aryl Trifluoromethyl Ethers. Satenik Mkrtchyan* Vishal B. Purohit, Jiří Zapletal, Oleksandr O. Shalimov, Jela Nociarová, Juraj Filo, Michael Garcia, Elena Kupcová, Barbora Benická, Viktor O. Iaroshenko.* 2024, conditionally accepted.

 

4. Mechanochemical Transformation of Aromatic Amines into Trifluoromethyl Arenes. Satenik Mkrtchyan*, Vishal B. Purohit, Jiří Zapletal, Oleksandr O. Shalimov, Viktor O. Iaroshenko.*

2024, conditionally accepted. 

 

5. Mechanochemical Synthesis of Aromatic Ketones: Pyrylium Tetrafluoroborate Me-diated Deaminative Arylation of Amides. Satenik Mkrtchyan,* Oleksandr Shalimov, Michael G. Garcia, Jiří Zapletala, Viktor O. Iaroshenko.* 2024, conditionally accepted. 

 

6. Nanocellulose as Reaction Media for FeCl3-mediated Mechanochemical Deaminative Fluorination of (Hetero)aromatic Amines. Satenik Mkrtchyan,*Oleksandr Shalimov, Vishal B. Purohit,Jiří Zapletal, Vaibhav D. Prajapati, Ronak V. Prajapati, Dhanasekar Elumalai, Michael G. Garcia, Juraj Filo, Barbora Benicka, Viktor O. Iaroshenko.* 2024, conditionally accepted. 

 

7. Mechanochemically enabled, Pyrylium tetrafluoroborate Mediated Deaminative Arylation of Aromatic Amines, Synthesis of Biphenyls. Satenik Mkrtchyan*, Oleksandr O. Shalimov, Jiří Zapletal, Michael Garcia, Viktor O. Iaroshenko.* 2024, conditionally accepted.

 

8. TM-catalyzed activation of free phenols in a one-step Suzuki-Miyaura cross-coupling under mechanochemical conditions. Satenik Mkrtchyan*, Michał Jakubczyk, Sehrish Sarfaraz, Khurshid Ayub, Viktor O. Iaroshenko.* 2024, conditionally accepted.

 

9. Mechanochemically enabled, Pyrylium tetrafluoroborate Mediated Deaminative Arylation of Aromatic Amines, Synthesis of Biphenyls. Satenik Mkrtchyan*, Oleksandr Shalimov, Michael Garcia, Jiří Zapletal, Juraj Filo, Mohanad Shkoor, Elena Kupcová, Barbora Benická, Viktor O. Iaroshenko.* 2024,submitted.

 

10. Dry Ice utilized Nickel-Catalyzed Mechanochemical Direct Carboxylation of Aryl Halides using nanocellulose as reaction media. Satenik Mkrtchyan,* Dhanasekar Elumalai, Vishal B. Purohit, Jiří Zapletal, Viktor O. Iaroshenko.* 2024,submitted.

 

Consultation hours

Monday
-
Thuesday
-
Wednesday
-
Thursday
-
Friday
-